Abundant non-hydrocarbons in crude oils from the western Qaidam Basin, northwest China
Yi Duan, Yaorong Qian, Chuanyuan Wang, Zhiping Wang, Xiaobao Zhang, Hui Zhang, Baoxiang Wu, Guodong Zheng
Geochemical Journal, Vol. 38, No. 5, P. 461-471, 2004
ABSTRACT
The non-hydrocarbon fraction of immature-low maturity crude oils from the western Qaidam Basin which were formed in the source beds deposited in highly saline and strongly reducing environments were analyzed by GC-MS to determine their compositions. Abundant fatty acids, alkanols, fatty acid glycerol monoesters, and stenols were identified. Geochemical analyses suggested that these compounds were largely originated from the oil source rocks. The linear compounds consist primarily of the short-chain homologues (C10–C20). The C27–C29 sterols detected were dominated by C27 stenols. The molecular characteristics suggest that algae and bacteria were the major source organism. The presence of abundant fatty acid glycerol monoesters suggests that the biological lipids, particularly bacterial phospholipids were important contributors to the formation of the crude oils studied. The existence of abundant unsaturated linear compounds, stenols and high CPI values of linear non-hydrocarbon compounds is consistent with the low maturity of these crude oils.
KEYWORDS
non-hydrocarbon, polar organic compound, fatty acid, alkanol, fatty acid glycerol monoester, crude oil
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