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Geochemistry of Middle Oligocene-Pliocene sandstones from the Nanpu Sag, Bohai Bay Basin (Eastern China): Implications for provenance, weathering, and tectonic setting

SHILIN LIU, GE LIN, YUNHUA LIU, YE ZHOU, FAXIONG GONG, YI YAN
Geochemical Journal, Vol. 41, No. 5, P. 359-378, 2007

ABSTRACT

Petrographic and geochemical compositions of thirty-seven Middle Oligocene-Pliocene sandstone samples from the Nanpu Sag in Bohai Bay Basin were analyzed to evaluate their provenance, weathering, and tectonic setting. These sandstones comprise mainly arkoses and lithic arenites and a few graywackes, characterized by low to moderate quartz/total feldspar ratios (1.31-6.11, average 2.72 ± 0.98) and CIA values (45.87-70.13, 57.49 ± 5.93). The Middle-Upper Oligocene sandstones have average lower SiO2 (71.72 ± 5.16%), and higher Fe2O3 (3.06 ± 1.26%) and MgO (1.65 ± 0.39%), in contrast with the Miocene samples that generally have high SiO2 (76.46 ± 4.26%) and low Fe2O3 (3.04 ± 1.51%) and MgO (0.69 ± 0.32%) contents. Following the deposition, Fe2O3 (3.17 ± 1.00%) and MgO (1.07 ± 0.38%) contents increased again in the Pliocene samples. Such a compositional variation trend is interpreted as a change of tectonic activity in the sag from Middle Oligocene to Pliocene, i.e., stronger in the Middle Oligocene, weaker in the Miocene and to stronger again in the Pliocene. Qt-F-L plot, trace element provenance discrimination diagrams (e.g., Eu/Eu*, Co/Th, and La/Sc), and REE characteristics suggest that the source rocks were mainly derived from felsic igneous rocks, possibly from Mesozoic granitoids and felsic volcanic lavas in the Yanshan Fold Belt. Tectonic discrimination diagrams (e.g., SiO2-K2O/Na2O, Fe2O3* + MgO-TiO2, and Th-Sc-Zr/10) show that these sandstones were mainly deposited in an active continental margin setting, implying a remobilized intra-continental environment.

KEYWORDS

petrography, geochemistry, provenance, tectonic setting, Nanpu Sag

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