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Geochemical Journal
Geochemical Journal An open access journal for geochemistry
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Published for geochemistry community from Geochemical Society of Japan.

Carbonate equilibria and the phase rule

Roland Wollast, Ricardo M. Pytkowicz
Geochemical Journal, Vol. 12, No. 3, P. 199-200, 1978

ABSTRACT

In this work the conditions required for the presence of two solid phases in equilibrium with a solution are discussed with special reference to the co-existence of magnesium calcites and dolomite in seawater. The criterion is determined in terms of the phase rule and of the solid-seawater ratio.

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