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Geochemical Journal
Geochemical Journal An open access journal for geochemistry
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Major and trace element chemistry and D/H, 18O/16O, 87Sr/86Sr and 143Nd/144Nd ratios of rocks from the spreading center of the Okinawa Trough, a marginal back-arc basin

Hiroji Honma, Minoru Kusakabe, Hiroo Kagami, Shigeru Iizumi, Hitoshi Sakai, Yukio Kodama, Masaaki Kimura
Geochemical Journal, Vol. 25, No. 2, P. 121-136, 1991

ABSTRACT

Basalts (OKTB) from the Okinawa Trough (OKT), which is a now opening marginal back-arc basin, are chemically quite similar to those from the intra-oceanic back-arc basins such as the Mariana Trough. Both olivine-normative and quartz-normative basalts occur, and major and trace element concentrations show a systematic variation, probably derived by differentiation of the magma. D/H, 87Sr/86Sr and 143Nd/144Nd ratios are almost identical in the dacite and basalts, and the 18O/16O ratio in the former is only slightly higher than in the latter, suggesting that the dacites are ultimately cognate with basalts. Concentrations of Al2O3, total iron, MgO, CaO, Na2O, Ni, Cr, and V in OKTB are within the range of variation in normal type mid-ocean ridge basalts (N-MORB), whereas OKTB have significantly higher K2O, Rb and Sr contents and D/H, 18O/16O and 87Sr/86Sr ratios and a lower 143Nd/144Nd ratio than N-MORB have. These chemical and isotopic features of OKTB can be well explained by the concept, which has been proposed by many authors for magma genesis in the intraoceanic back-arc basins, that the H2O-rich primary magma is generated from normal-type mantle peridotite modified by component from the subducted slab. Compared with those from intra-oceanic back-arc basins, the rocks from the OKT have distinctly higher 87Sr/86Sr and lower 143Nd/144Nd ratios, reflecting the higher contribution of continent-derived sedimentary components to the magma source. Oxygen, Sr and Nd isotopic characteristics of the rocks of the OKT are fitted well with paired two-component mixing models: one for the source-mixing and another for the crustal contamination.

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